Tylecote, R. F. and Thomsen, R. (1973). The segregation and surface enrichment of arsenic and phosphorus in early iron artefacts. Archaeometry 15. Vol 15, pp. 193-198.

Title
Title
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Title:
The segregation and surface enrichment of arsenic and phosphorus in early iron artefacts
Issue
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Issue:
Archaeometry 15
Series
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Series:
Archaeometry
Volume
Volume
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Volume:
15
Page Start/End
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Page Start/End:
193 - 198
Biblio Note
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Biblio Note
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Publication Type
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Publication Type:
Journal
Abstract
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Abstract:
Previous work on iron-arsenic alloys has shown that considerable superficial arsenic enrichment occurs during oxidation at high temperatures. This process could well explain the layers of high arsenic concentration often observed in the micro-structure of early (Roman to Viking) iron artefacts. Experiments have been made to determine how far the alternative theory of the use of Fe-As alloys as joining media could be responsible. These alloys can in some cases facilitate joining, but the result is an embrittled joint; when the arsenic content is reduced sufficiently to avoid this there is then no advantage over the normal hammer-welding without an arsenic layer. Similar experiments carried out with phosphate led to similar conclusions. Au(adp)
Author
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Author:
Ronald F Tylecote
R Thomsen
Year of Publication
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Year of Publication:
1973
Locations
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Subjects / Periods:
Iron Artefacts (Auto Detected Subject)
Iron (Auto Detected Subject)
EARLY MEDIEVAL (Historic England Periods)
MEDIEVAL (Historic England Periods)
ROMAN (Historic England Periods)
Source
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Source:
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BIAB (British Archaeological Abstracts (BAA))
Created Date
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Created Date:
05 Dec 2008