Girbal, B. (2011). Roman and Medieval Litharge Cakes : A Scientific Examination. Fort Cumberland: Historic England. https://doi.org/10.5284/1046894. Cite this using datacite

Title
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Title:
Roman and Medieval Litharge Cakes : A Scientific Examination
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Series:
Historic England Research Reports
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Downloads:
englishh2-310634_1.pdf (17 MB) : Download
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DOI
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DOI
https://doi.org/10.5284/1046894
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Publication Type:
Report (in Series)
Abstract
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Abstract:
The refining of silver alloys to obtain the silver they contain (cupellation) has been undertaken for thousands of years. The primary material evidence for this process comprises a lead-rich waste known as litharge cakes. Studies conducted by Bayley and Eckstein (2006) and Bayley (2009) suggested that cupellation in the medieval period was more successful/advanced than in Roman times based on the higher PbO/Cu2O ratio in the medieval litharge cakes. The analyses of a further forty five litharge fragments from twelve archaeological sites has found no correlation between the PbO/Cu2O ratio and time period. The microstructural and chemical analyses showed that there were two major compositions; a clay/vegetable ash mixture and bone ash. No correlation was identified between hearth lining composition and the PbO/Cu2O ratio. However, it is argued that the clay/vegetable ash was more absorbent than the bone ash litharge cakes. It was also noticed that 90% of the medieval litharge was clay/vegetable ash while they accounted for only 50% of the Roman litharge. This may be indicative of a compositional preference in certain time periods. Unfortunately the dating is poor in most cases limiting more comprehensive interpretations. Nevertheless there is no evidence to suggest a more effective practice at either period.
Author
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Author:
B Girbal
Publisher
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Publisher:
Historic England
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Other Person/Org:
Historic England (OASIS Reviewer)
Please note: this record has been validated by-proxy by Historic England.
Year of Publication
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Year of Publication:
2011
Locations
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Locations:
Site: No.1 Poultry
County: Greater London
District: City of London
Parish: CITY OF LONDON
Country: England
Grid Reference: 532580, 181100 (Easting, Northing)
Subjects / Periods
Subjects / Periods
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Subjects / Periods:
MEDIEVAL (Historic England Periods) LITHARGE (Object England)
ROMAN (Historic England Periods) LITHARGE (Object England)
MEDIEVAL (Historic England Periods) SITE (Monument Type England)
ROMAN (Historic England Periods) SITE (Monument Type England)
FIELD SURVEY (Event)
Identifiers
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Identifiers:
OASIS Id: englishh2-310634
OBIB: 51/2011
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A4 bound report of 80pp.
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OASIS (OASIS)
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Created Date
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Created Date:
05 Apr 2018