Title: |
Roman and Medieval Litharge Cakes : A Scientific Examination |
Series: |
Historic England Research Reports
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Downloads: |
englishh2-310634_1.pdf (17 MB)
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Licence Type: |
ADS Terms of Use and Access
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DOI |
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Publication Type: |
Report (in Series)
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Abstract: |
The refining of silver alloys to obtain the silver they contain (cupellation) has been undertaken for thousands of years. The primary material evidence for this process comprises a lead-rich waste known as litharge cakes. Studies conducted by Bayley and Eckstein (2006) and Bayley (2009) suggested that cupellation in the medieval period was more successful/advanced than in Roman times based on the higher PbO/Cu2O ratio in the medieval litharge cakes. The analyses of a further forty five litharge fragments from twelve archaeological sites has found no correlation between the PbO/Cu2O ratio and time period. The microstructural and chemical analyses showed that there were two major compositions; a clay/vegetable ash mixture and bone ash. No correlation was identified between hearth lining composition and the PbO/Cu2O ratio. However, it is argued that the clay/vegetable ash was more absorbent than the bone ash litharge cakes. It was also noticed that 90% of the medieval litharge was clay/vegetable ash while they accounted for only 50% of the Roman litharge. This may be indicative of a compositional preference in certain time periods. Unfortunately the dating is poor in most cases limiting more comprehensive interpretations. Nevertheless there is no evidence to suggest a more effective practice at either period. |
Author: |
B Girbal
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Publisher: |
Historic England
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Other Person/Org: |
Historic England (OASIS Reviewer)
Please note: this record has been validated by-proxy by Historic England.
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Year of Publication: |
2011
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Locations: |
Site: |
No.1 Poultry |
County: |
Greater London |
District: |
City of London |
Parish: |
CITY OF LONDON |
Country: |
England |
Grid Reference: 532580, 181100 (Easting, Northing)
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Subjects / Periods: |
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Identifiers: |
OASIS Id: |
englishh2-310634 |
OBIB: |
51/2011 |
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Note: |
A4 bound report of 80pp.
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Source: |
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Relations: |
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Created Date: |
05 Apr 2018 |