Chu, V., Regev, L., Weiner, S. and Boaretto, E. (2008). Differentiating between anthropogenic calcite in plaster, ash and natural calcite using infrared spectroscopy:. J Archaeol Sci 35 (4). Vol 35(4), pp. 905-911.

Title
Title
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Title:
Differentiating between anthropogenic calcite in plaster, ash and natural calcite using infrared spectroscopy:
Subtitle
Subtitle
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Subtitle:
implications in archaeology
Issue
Issue
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Issue:
J Archaeol Sci 35 (4)
Series
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Series:
Journal of Archaeological Science
Volume
Volume
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Volume:
35 (4)
Page Start/End
Page Start/End
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Page Start/End:
905 - 911
Biblio Note
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Biblio Note
Please note that this is a bibliographic record only, as originally entered into the BIAB database. The ADS have no files for download, and unfortunately cannot advise further on where to access hard copy or digital versions.
Publication Type
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Publication Type:
Journal
Abstract
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Abstract:
Infrared spectroscopy provides information not only on the type of calcium carbonate polymorph, but also on the extent of atomic order. In calcite, three major infrared absorption peaks are identified: ν3, νv2, and v4. It was shown that the ratio between v2 and v4 bands reflects the order of the calcite crystal structure. In this paper the authors analyse this ratio in geologically formed calcites, archaeological plasters, modern plasters and experimentally prepared plasters. For the geological calcite, the values of the v2/v4 ratio are around 3, whereas for the experimentally prepared plasters, the values are around 6.5. The v2/v4 ratio for archaeological plasters varies from 3 to 6. This shows that a high ratio is indicative of disorder in the crystal, and implies that the calcite was formed from calcium oxide at high temperatures. It also implies that this disorder can be preserved for at least 14,000 years. The v2/v4 ratio of calcite from archaeological sites can thus be used to differentiate between anthropogenic calcite, such as in plaster, mortar and wood ash, from geogenic calcite, such as in limestone. The ratio may also be used to identify plaster or ash that still retains its original crystals and therefore carbon-14 content.
Author
Author
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Author:
Vikki Chu
Lior Regev
Steve Weiner
Elisabetta Boaretto
Year of Publication
Year of Publication
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Year of Publication:
2008
Locations
Locations
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Subjects / Periods:
Wood Ash (Auto Detected Subject)
Ash (Auto Detected Subject)
Crystal Structure (Auto Detected Subject)
Plaster Ash (Auto Detected Subject)
Mortar (Auto Detected Subject)
Source
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Source:
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BIAB (The British & Irish Archaeological Bibliography (BIAB))
Created Date
Created Date
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Created Date:
23 Jul 2008